The reaction rate of low-temperature steam reforming was studied over two Ni-based catalysts. Experimental tests were carried out for temperatures between 400 and 550 °C and pressures between 1 and 7 bar, using methane and simulated biogas (1:1 methane-carbon dioxide mixture) as carbonaceous feed. The results were analyzed with a simplified reaction rate expression. The parameters of such expression were optimized in order to provide a tool for the design of an industrial scale reactor using the catalysts considered.
Kinetic assessment of Ni-based catalysts in low-temperature methane/biogas steam reforming / Turchetti, L; Murmura, MARIA ANNA; Monteleone, G.; Giaconia, A.; Lemonidou, A. A.; Angeli, S. D.; Palma, V.; Ruocco, C.; Annesini, Maria Cristina. - In: INTERNATIONAL JOURNAL OF HYDROGEN ENERGY. - ISSN 0360-3199. - STAMPA. - 41:38(2016), pp. 16865-16877. [10.1016/j.ijhydene.2016.07.245]
Kinetic assessment of Ni-based catalysts in low-temperature methane/biogas steam reforming
MURMURA, MARIA ANNA;ANNESINI, Maria Cristina
2016
Abstract
The reaction rate of low-temperature steam reforming was studied over two Ni-based catalysts. Experimental tests were carried out for temperatures between 400 and 550 °C and pressures between 1 and 7 bar, using methane and simulated biogas (1:1 methane-carbon dioxide mixture) as carbonaceous feed. The results were analyzed with a simplified reaction rate expression. The parameters of such expression were optimized in order to provide a tool for the design of an industrial scale reactor using the catalysts considered.File | Dimensione | Formato | |
---|---|---|---|
Turchetti_Kinetic-assessment-Ni_2016.pdf
solo gestori archivio
Tipologia:
Versione editoriale (versione pubblicata con il layout dell'editore)
Licenza:
Tutti i diritti riservati (All rights reserved)
Dimensione
972.49 kB
Formato
Adobe PDF
|
972.49 kB | Adobe PDF | Contatta l'autore |
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.